Here is a list of great free software apps and tools available from Microsoft
Ultimate List of Free Windows Software from Microsoft
Some of my favorites:
SyncToy – helps copy, move, and synchronize files with digital cameras, e-mail, cell phones, portable media players, camcorders, PDAs, and laptops.
Fiddler – a HTTP Debugging Proxy which logs all HTTP traffic [...]

Sysinternals is an excellent suite of tools by Mark Russinovich (now working in Microsoft) that should be in everyone’s toolkit.
Download Sysinternals Suite
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Starting this year in 2007, the start date and the end date for daylight saving time (DST) in the United States will change. DST in the United States will start three weeks earlier and will end one week later than in previous years. DST will start at 2:00 A.M. on the second Sunday in March [...]